Paris Saint-Germain
His performances in the FIFA Club World Cup attracted the attention of French side Paris Saint-Germain, who brought him to the French capital in the summer of 2007, for R$6,752,750 and keeping him until 2010. Ceará made his debut for the club, coming on as substitute after 84 minutes for Amara Diané in a match against AS Monaco which PSG won 2–1 on 16 September 2007. The next game on 6 October 2007, Ceará scored his goal for the club in a 3–1 loss against Stade Rennais. On 15 March 2008, Ceará scored an own goal in a 1–1 against Valenciennes which PSG were losing until Pauleta equalizer give both clubs a draw. In his first season, Ceara struggled to find his best form, and made a few high-profile mistakes that contributed to a poor campaign for his club. In the Coupe de la Ligue Final, Ceará played in the right back as PSG won the Coupe de la Ligue for third time against Lens 2–1 with a winning goal from substitute Bernard Mendy on stoppage time.
As from 2008 to 2009, the Brazilian's displays improved and he's since considered as one of the most reliable performers in the squad, where he
made almost every league game remained scoreless, but this year, but made with four assists, twice as many as they did in previous season and also support and agreement field with Ludovic Giulyband Stéphane Sessègnon. He also involved in UEFA Cup where he provided 3 assist in 9 UEFA Cup before losing to Ukrainian side Dynamo Kyiv 3–0. What made it worse when PSG became sixth place which resulted missing out on Europa League qualification or play-off-grid positions and didn't win either Coupe de France (eliminated in Round of 16) and Coupe de la Ligue (eliminated in semi-final), without winning a single title.
The following season in 2009/10, the club appointed a new manager Antoine Kombouaré after Paul Le Guen left due to expiry of his contract. Prior the season started, Ceará signed a new contract at PSG until 2012 as his contract was to expire next summer. Ceará find himself in spite of the arrival of competitor Christophe Jallet in the summer of 2009 and face competition with Jallet whether who take the right back position. At the start of the season, Ceará played a few games due to injury. Later on the season, Ceará made more appearance in the season. By the end of the season, Ceará made 29 appearances and 1 assist when he set up a goal for Jérémy Clément to score the only goal in a match against Auxerre on 28 November 2009. The team became thirteen place which the club briefly represented in the relegation battle. Despite bad performance in the league, Ceará was on the bench for the final until he come on for Mevlüt Erdinç on 105 minutes as PSG won the Coupe de France for the eighth time in a 1–0 against AS Monaco, thanks to Guillaume Hoarau who scored a winning goal in extra time. Despite the Coupe de France, the club also participate in Emirates Cup (which they became second) and Trophée des Champions where they lose to Le Classique rival Olympique de Marseille on penalties following Ludovic Giuly missed and Édouard Cissé struck the winning penalty to win the cup.
The following season in 2010/11, Ceará suffered a performance hit following initially good phase which goes back including an injury he suffered in its early phase of the new season. After initially always acted on the full playing time, he also worked to recover from injury to join the team as a regular force, which he did sometimes. But even after it had returned to the team found, he was only partly to do sporadic occasions in February 2011 and was only used as a substitute for a few minutes. Its so far (as of 30 March 2011) last championship when he joined on 27 February 2011 with a 2–1 home victory over Toulouse. In November 2010, Ceará had to have a nose surgery after being elbowed to the face in a 1–1 draw against Lorient. 14 days later on 28 November 2010, Ceará able to make a return in a 2–2 draw against Olympique Lyonnais. However, Ceará was able to get more playing time in the UEFA Europa League where he played 9 games of 12 match. PSG beat Israeli side Maccabi Tel Aviv 5–4 aggregate in the play-off round to go Group Stage. At the group stage, PSG was the top of the table of Group J. In the Knockout stage, PSG beat BATE Borisov on away goal in first round before being eliminated in last 16 by Portuguese side Benfica 3–2 on aggregate, thus out of Europa League. Also, PSG once again progress into the final against Ligue 1 winner Lille where he made a start in the right back but Lille won 1–0 thanks to Ludovic Obraniak.
The following season in 2011/12, Ceará was linked with Brazilian side Santos who offered him a three-year contract but he rejected made the choice of the heart and on 16 September 2011, he signed a one-year deal, extend his stay until 2013. With the arrival of Qatar Investment Authority and director of football Leonardo changing it ownership, the club signed prestigious players and sign new defenders like Milan Biševac and Diego Lugano. In Europa League Qualification first leg against FC Differdange 03, Ceará scored his first of the season in a 4–0 win, which followed up a 2–0 win in second leg. On 25 February 2012, Ceará scored his first goal in five years in a 4–4 draw against Olympique Lyonnais. In December 2011, Kombouaré was sacked and replaced by Carlo Ancelotti. Under Ancelotti, Ceará face competition from defenders following arrivals of Brazilians Alex and Maxwell. Ceará then lost his place in the right back position as Ancelotti preferred Biševac. Ceará feels that their manager Ancelotti why he offered no explanation as to why he has been dropped and admits his situation is unlikely to change any time soon and claims to be at a loss to explain his snub, with no-one having communicated to him why he now finds himself on the bench. Later on the season, Ceará spend times on the bench without getting any playing time. By the end of season, PSG released Ceará after spending five years at the club.