1992-95: End of MCA tenure
His next MCA album, This One's Gonna Hurt You, came out in 1992. The lead single "This One's Gonna Hurt You (For a Long, Long Time)", also a duet with Tritt, was a top-10 hit in 1992, but the followup singles, "Now That's Country", "High on a Mountain Top", and "Hey Baby", were less successful. Kennerley and Cash were once again among the contributing vocalists, while Ashley Cleveland and Pam Tillis both sang backing vocals on "High on a Mountain Top". Johnny Cash provided duet vocals on "Doin' My Time", while the track "Me and Hank and Jumpin' Jack Flash" sampled voice recordings of Lester Flatt, Hank Williams, and Ernest Tubb. Alanna Nash of Entertainment Weekly rated the album "A", finding the "stylistic mix" superior to preceding albums, noting influences of bluegrass, Southern rock, rockabilly, and blues in his delivery and song choices. Also in 1992, Columbia issued Let There Be Country. This One's Gonna Hurt You was certified gold by the RIAA in 1993. Stuart won his second Grammy Award in 1993, in the category of Best Country Instrumental Performance, as one of several featured artists on Asleep at the Wheel's cover of "Red Wing" on their 1993 album Tribute to the Music of Bob Wills and the Texas Playboys.
Love and Luck was his next album, released in 1994. Only one single, "Kiss Me, I'm Gone", made top 40 from the project. Stuart co-produced the album with Brown, while also contributing on guitar, mandolin, and songwriting. The album's opening title track featured Vince Gill, Ricky Skaggs, and Harry Stinson on backing vocals. Also included were two covers: Billy Joe Shaver's "If I Give My Soul" and The Flying Burrito Brothers' "Wheels", as well as the mandolin instrumental "Marty Stuart Visits the Moon". Daniel Gioffre of AllMusic highlighted these three tracks in particular as being among the strongest on the album. Nash rated the album "B", stating, "As a singer, Marty Stuart has all the zip of unbuttered toast, and as a writer, too many of his songs float aimlessly...Yet Stuart has genuine love for the early country greats and injects his own work with such impassioned strains of old hillbilly styles, that he charms in spite of his limitations."
Following this album, MCA issued a compilation called The Marty Party Hit Pack in 1995, which contained singles from his previous MCA albums, as well as "The Whiskey Ain't Workin'", the previously unreleased "The Likes of Me" and "If I Ain't Got You", and two cover songs previously found on multi-artist tribute albums released in 1994. These were a rendition of Elvis Presley's "Don't Be Cruel", featuring The Jordanaires and previously found on It's Now or Never: The Tribute to Elvis, and The Band's "The Weight", featuring The Staple Singers and previously found on Rhythm, Country and Blues. Both of these cover songs were produced by Don Was, while Don Cook handled production on the two new songs. "The Likes of Me" was previously cut by Conway Twitty on his 1993 album Final Touches, on which Cook was also a producer. Both of these new songs were issued as singles in 1995, but neither entered the country music top 40. Jay Orr of New Country magazine criticized "The Likes of Me" and the two cover songs, but otherwise found the album a "neat summation" of Stuart's music. The Marty Party Hit Pack became Stuart's fourth and final gold album in 1998.
Stuart released Honky Tonkin's What I Do Best in 1996, which produced two more minor chart entries in the title track (another duet with Tritt) and "You Can't Stop Love" that year. The title track also won Stuart a Vocal Event of the Year award from the Country Music Association. Nash rated the album "A−", finding an influence of the Beatles in "Thanks to You" and of Delta blues in "The Mississippi Mudcat and Sister Sheryl Crow".