U.S. Supreme Court
On February 26, 1841, outgoing President Martin Van Buren, a Democrat, nominated Daniel as an associate justice of the Supreme Court, again to succeed Barbour (who had died). As Daniel's nomination to the Court was made during the final days of Van Buren's term, and with his elected successor William Henry Harrison of the Whig party due to take office on March 4, 1841, Senate Whigs opposed confirmation. Nonetheless, Daniel was confirmed by a wide 25–5 margin on March 2, 1841. His service on the Supreme Court began on January 10, 1842, and ended May 31, 1860, upon his death.
Daniel was the most frequent dissenter in the Taney Court with nearly two-thirds of his opinions going against the majority. Of the seventy-four opinions he wrote, fifty were dissents. His political views were reactionary and made the other justices around him seem moderate in comparison. He was arguably the strongest supporter of slavery on the Taney Court, and he also disagreed with the amount of power that was given to the federal government. He wrote a concurrence in Prigg v. Pennsylvania (1842) which upheld the Fugitive Slave Act of 1793. Daniel wrote:
Concurring entirely, as I do, with the majority of the court, in the conclusions they have reached relative to the effect and validity of the statute of Pennsylvania now under review, it is with unfeigned regret that I am constrained to dissent from some of the principles and reasonings which that majority, in passing to our common conclusions, have believed themselves called on to affirm.
He also joined the majority in Jones v. Van Zandt (1847) and wrote another concurring opinion a decade later in Dred Scott v. Sandford, to state that "the African negro race never have been acknowledged as belonging to the family of nations."
Justice Daniel authored only one significant opinion, West River Bridge Co. v. Dix, 47 U.S. (6 How.) 507 (1848), in his eighteen years on the nation's highest court.